Mass Spectrometry Laboratory (CHIM/03)

Attività di ricerca

Gas-phase ion and neutral chemistry: ion-molecule reactions as simple models for bond activation reactions relevant to catalytic processes occurring at the active sites, such as single-atom catalysis; detection and characterization of new radical and neutral species relevant to inorganic chemistry and atmospheric chemistry; measurement of thermochemical data and kinetic rate constants; studies of multiply charged ions undergoing bond-forming chemical reactions; analysis of pollutants in air and water samples; studies of the decomposition routes of biomasses relevant to the formation of platform molecules.

Collaborazioni nazionali e internazionali
  • Prof. M. Rosi, University of Perugia
  • Prof. A. Ricci, University of Campania L. Vanvitelli
  • Prof. P. Tagliatesta, University of Rome Tor Vergata
  • Prof. Y.-H. Ding, Jilin University of Changchun
  • Prof. K. Kirchner, Vienna University of Technology             
     
Strumentazione
  • Double-focussing mass spectrometer ZabSpec oa-TOF
  • linear ion trap LTQ-XL ThermoFisher
  • ion trap AmaZone Bruker
  • triple quadrupole CG Quattro Micro Waters
  • mass spectrometer tandem Q-TOF Waters Ultima
  • mass spectrometer MALDI-TOF Voyager DE (Perspective Biosystem) equipped with a N2 laser by Spectra Physics VSL337ND
  • GC Clarus 500 (Perkin Elmer) equipped with a FID detector
  • mass spectrometer Clarus 500 (Perkin Elmer).
Settori ERC
  • PE4 - Physical and Analytical Chemical Sciences: Analytical chemistry, chemical theory, physical chemistry/chemical physics
  • PE4_12 -Chemical reactions: mechanisms, dynamics, kinetics and catalytic reactions
  • PE4_2 -Spectroscopic and spectrometric techniques
Pubblicazioni

Pubblications (2015-2018):

1. A. Troiani, M. Rosi, S. Garzoli, C. Salvitti, G. de Petris
Iron-Promoted C-C Bond Formation in the Gas Phase.
Angew. Chem. Int. Ed. 54, 14359 (2015)

2. F.-F. He, S.-M. Gao, M. Rosi, G. de Petris, Y.-H. Ding Monocyclic and bicyclic CO4: how stable can they be?
RSC Advances 5, 91581 (2015)

3. A. Ricci, B. Di Rienzo, S. Piccolella, F. Pepi, S. Garzoli, P Giacomello
Acid Catalyzed Glucose Dehydration in the Gas Phase: a Mass Spectrometric Approach.
J. Mass Spectrom. 50, 228 (2015)

4. A. Ricci, B. Di Rienzo, F. Pepi, A. Troiani, S. Garzoli, C. Salvitti, P. Giacomello
A mass spectrometric study of the acid-catalysed D-fructose dehydration in the gas phase.
Carbohydrate Research413, 145 (2015 )

5. S. Garzoli, A. Pirolli, E. Vavala, A. Di Sotto, G. Sartorelli, M. Božović, L. Angiolella, G. Mazzanti, F. Pepi, R. Ragno, Multidisciplinary Approach to Determine the Optimal Time and Period for Extracting the Essential Oil from Mentha suaveolens Ehrh
Molecules20, 9640 (2015)

7. F.-F. He, S.-M. Gao, M. Rosi, G. de Petris, Y.-H. Ding
Isomerization Pathways of ONCNO: Unstable or Metastable?
J. Phys. Chem. A 120, 4812 (2016)

8. A. Ricci, F. Pepi, P. Cimino, A. Troiani, S. Garzoli, C. Salvitti, B. Di Rienzo, V. Barone
Vitamin C: An Experimental and Theoretical Study on the Gas Phase Structure and Ion Energetics of Protonated Ascorbic Acid
Journal of Mass Spectrometry 51, 1146 (2016)

9. A. Troiani, M. Rosi, S. Garzoli, C. Salvitti, G. de Petris
Vanadium Hydroxide Clusters in the Gas Phase: Bond-Forming Reactions of Doubly-Charged Negative Ions by SO2-promoted V-O Bond Activation.
Chemistry- Eur. J. 23 , 11752 (2017)

10. S. R. M. M. de Aguiar, Ö. Öztopcu, A. Troiani, G. de Petris, M. Weil, B. Stöger, E. Pittenauer, G. Allmaier, L. F. Veiros, K. Kirchner
Formation of Mono Oxo Molybdenum(IV) PNP Pincer Complexes: Interplay between Water and Molecular Oxygen.
Eur. J. Inorg. Chem. 876 (2018)

11. A. Troiani, M. Rosi, S. Garzoli, C. Salvitti, G. de Petris
Sulfur Dioxide Cooperation in Hydrolysis Reactions by Vanadium Oxide and Hydroxide Cluster Dianions.
New J. Chemistry 42, 4008 (2018)

12. L. Antonini, S. Garzoli, A. Ricci, A. Troiani, C. Salvitti, G. Giacomello, R. Ragno, A. Patsilinakos, B. Di Rienzo, F. Pepi
Ab-initio and experimental study of pentose sugar dehydration mechanism in the gas phase. Carbohydrates Research, 458-459, 19-28 (2018).

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